The Difference Between German DIN Ozone Design and North American Pool Standards
German DIN standards are the highest level of sanitation for pool water in the world. This standard is in
accordance with drinking water standards. This is because water is absorbed by swimming pool patrons (approx. ½
litre/hour). The reasoning is if water is being absorbed by swimmers, then they should only be absorbing water that
is fit to drink. Hence, the German standards are in accordance with drinking water treatment.
The process to produce German water standards is rigorous. The water in the pool is actually treated with Ozone
on the way out of the pool. Ozone is then given time to do its work (referred to as the CT value - Concentration x
Time) in an overflow pool, which is anywhere from 25 - 35% of the total pool volume. After sufficient time to
oxidize organics, chlorine residuals, chloramines and other pollutants in the water, the water is then put through a
mechanical filtration process. At the end of the filtration process is a GAC or Granular Activated Carbon (GAC)
filter. This is a chemical filter that is designed to remove Disinfection Byproducts (DB’s). The Disinfection
Byproducts are chemical hazards such as Trihalomethanes (THMs), chloroform, chloramines (bound chlorines)
and other known carcinogens. These disinfection byproducts are formed mainly by Chlorine.
After the GAC filtration, a chlorine residual is added to the water before it is pumped back into the swimming
pool.
The German Model
In the German model, the entire thrust of the standard is to not expose swimmers to the hazards of chlorinated
disinfection byproducts (what we call bound chlorine in swimming pools) and to supply water to the swimmer that
is in accordance with accepted drinking water standards. This is why the water is treated on the way out of the
pool. Most of the harmful
disinfection byproducts formed by
the reaction of chlorine and
organics are then done in a
controlled manner in the overflow
pool, where swimmers are not
exposed to this process. Ozone can
safely remove the bound chlorines,
organics and other pollutants in a
controlled manner in this overflow
pool. Since only a slight residual of
chlorine is used on the water
flowing back into the pool, the
levels of Trihalomethanes,
chloramines (bound chlorine) and
other chlorine disinfection
byproducts are kept to a minimum
(as per drinking water regulations).
North American Swimming Pool Design
North American pools are generally designed so that a high level of chlorine is added to the water flowing into the
pool. There is generally no overflow pool for the controlled oxidation of organics and other pollutants and
“breakpoint chlorination” is done to remove disinfection byproducts. In other words, the same technology that
created the disinfection byproducts is then done at a very high level to oxidize them so the filters can remove them.
This exposes pool patrons to high levels of chlorine, chloramines, THM’s and other pollutants inside the pool area.
As well, chlorine off-gassing takes place in the pool facility itself. Generally, there is no accounting for exposure
of the pool patrons to chloramines, bound chlorine, THM’s, chloroform and other disinfection byproducts in the
pool design. The water in a typical North American swimming pool is not fit to drink under current drinking water
standards because of elevated THM’s and other chemicals.
Why North American Swimming Pool Design Differs
After World War II with the advent of chlorine, it was assumed that water safety concerns ie. E-coli and other
serious water-borne bacteria would be a thing of the past. Conventional wisdom was that chlorine could be safely
used in swimming pools to kill
problem bacteria and simple
filtration systems could be used to
keep the water clear. Chlorine
equipment was a low capital
investment and gained most of the
market share. Thus, most
swimming pools were designed
with a simple chlorination and
filtration process and standards
were set up accordingly.
With the recognition of problems
with disinfection byproducts, most
notably in drinking water standards
in European countries, the
emphasis shifted away from
chlorine only models of water
disinfection. While chlorination provided protection against bacteria, it also created a host of other health problems
that are increasingly being recognized around the world. (Saskatchewan, for example, recently lowered the
allowable THM’s in drinking water after studies showed an increased danger of miscarriage).
The Ozone Retrofit
Most North American pool facilities can not afford to retrofit to the exacting German DIN standards. However,
Ozone can still be used to reduce the overall ill effects of Chlorine and chlorinated Disinfection Byproducts in the
pool water. This includes a
significant reduction in overall
chloramines, THM’s, chloroform
and other bound chlorines in the
water and effective reductions of
chlorine off-gassing in the pool
area.
Envron has designed an Ozone
swimming pool retrofit that takes
advantage of the existing filtration
system without the need for the
addition of large high-volume
water tanks. Envron’s design
reduces the overall chlorine
requirements in the pool, reduces
the chlorinated off-gassing that
takes place in the pool and
virtually eliminates the need for
breakpoint chlorination or
“shocking” the pool. Ozone also eliminates the needs for secondary chemicals for keeping scale out of pipes etc.
As well, the pool filtration system is enhanced and water turns crystal clear and sparkling (overall pool turbidity is
decreased dramatically.)
Sidestream Ozonation
Sidestream Ozonation is used in numerous industries where Ozone is required to be added to large amounts of
water and Ozonating the entire water stream would be impractical (which is the case in most swimming pool
retrofits). Because the technology to accomplish this has been in use for decades, the application to pool water is
straightforward. The equipment used to accomplish this is readily available and is simple to operate. An Ozone
contacting/off-gas system is used to divert part of the flow of the main pool water to the Ozonation equipment.
There, Ozone is added to the water and any Ozone off-gas is safely destroyed. The dissolved Ozone/water mixture
is then returned to the main pool flow and the filtration system.
Advantages of Sidestream Ozonation
The advantages of Sidestream Ozonation include oxidation of organics, which then clump together and are able to
be removed by the filtration system. Since Ozone is a micro-flocculent, the entire filtration system is much more
efficient. Ozone will partially oxidize organics in the pool water. This means that the organics become “sticky” and
will clump together. (This is done on a microscopic level). When organics clump together, they can then be trapped
by the filter system. The water quickly becomes saturated with Oxygen and turns crystal clear and sparkling.
Turbidity is decreased. The pool system is put in a constant state of “shock” and breakpoint chlorination is
effectively eliminated. The levels of bound chlorine is reduced in the pool water. Chlorine off-gassing is also
effectively eliminated.
The overall increase in the health of the water and the health of the entire pool area increases dramatically over
Chlorination systems alone.
An Upgrade Path
Envron’s systems also allow an upgrade path. Once the basic sidestream Ozonation system is installed, it can be
upgraded to an ORP-controlled system. ORP control means, in most jurisdictions, that a smaller residual of
chlorine is required (ie. in some jurisdictions for example, maintaining a 650 ORP means that the free chlorine
required drops from 2 mg/L to .6 mg/L.)